Mesityl(2,2,2-trifluoroethyl)iodonium trifluoromethanesulfonate

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
2,2,2-trifuoroethyl(mesityl)-iodonium triflate
Trifluoroethylating Reagents
KUMI6F06
1660142-41-5
 

27966252
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Melting Point
Packaging
Storage
Mesityl(2,2,2-trifluoroethyl)iodonium trifluoromethanesulfonate
CF3O3S*C11H13F3I
478.19
≥96%(HPLC)
White Solid
112-114ºC
5g,10g,25g,50g and 100g
Store at room temperature
Mesityl(2,2,2-trifluoroethyl)iodonium trifluoromethanesulfonate is a novel electrophilic trifluoroethylating reagent for directly introduce trifluoroethyl group to target compounds (e.g. indoles, aromatics, arylbornic acids) via C-H activation.
Efficient direct 2,2,2-trifluoroethylation of indoles via C–H functionalization. [1]
Mild and Efficient Palladium-Catalyzed Direct Trifluoroethylation of Aromatic Systems by C-H Activation. [2]
Pd-catalyzed divergent trifluoroethylation and arylation of arylboronic acids by aryl(2,2,2-trifluoroethyl)iodonium triflates. [3]
Direct ortho-Trifluoroethylation of Aromatic Ureas by Palladium Catalyzed C-H activation: A Missing Piece of Aromatic Substitutions. [4]
References:
[1] G. L. Tolnai, et al, Chem. Commun., 2015, 51, pp 4488-4491.
[2] B. L.Tót, et al , Angewandte Chemie, 2016, 55(6), pp 1988-1992.
[3] J.Yang, et al, Org. Biomol. Chem., 2016, 14, pp 7654-7658.
[4] S. Kovács, et al, Adv.Syn. Cata., 2017, 359(3), pp 527-532.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
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