PhSCF2CF2SiMe3 is employed as a tandem anion and radical tetrafluoroethylene equivalent for the introduction of a CF2CF2 moiety. e.g. this reagent can provide a fluoride-catalyzed nucleophilic addition to N-substituted cyclic amides and carbonyl compounds affording the corresponding adducts.
Development of PhSCF2CF2SiMe3 as a tandem anion and radical tetrafluoroethylene equivalent: Preparation of tetrafluoroethyl-substituted alcohols and tetrafluorotetrahydropyrans. 
Application of PhSCF2CF2SiMe3 as a Tandem Anion and Radical Tetrafluoroethylene Equivalent: Fluoride-Catalyzed Addition to N-Substituted Cyclic Imides Followed by Radical Cyclization. 
 Y.Chernykh, K.Hlat-Glembová, P. Hajek, B. Klepetářová,P.Beier, Eur. J.Org. Chem., 2011, 24, pp 4528-4531.
 Y.Okorochenkova, S.Opekar, B. Klepetářová, P.Beier, Synlett.,2012, 23(8), pp 1187-1190.
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