Trifluoromethaneselenenyl chloride

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
Trifluoromethyl selenohypochlorite,CF3SeCl
Trifluoromethylselenolating Reagents
KUMI3F50
1495-26-7
 
11735551
1734708
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Boiling Point
Packaging
Storage
Trifluoromethaneselenenyl chloride
CClF3Se
183.43
≥98.0%
Cherryred to Red Liquid
22-31ºC
5ml,10ml,50ml,100ml,500ml and 1L
Store at 2-8ºC temperature
Trifluoromethaneselenenyl chloride (CF3SeCl) is an electrophilic reagent for direct trifluoromethylselenolation of electron rich arenes( including anilines derivatives and phenol) and diethyl malonate sodium salt.
A mild and practical preparation of trifluoromethaneselenenyl chloride. [1]
Benzyltrifluoromethyl (or Fluoroalkyl) Selenide: Reagent for Electrophilic Trifluoromethyl (or Fluoroalkyl) Selenolation. [2]
Electrophilic Trifluoromethyl- and Fluoroalkylselenolation of Organometallic Reagents. [3]
Trifluoromethyl- and Fluoroalkylselenolations of Alkynyl Copper(I) Compounds. [4]
Copper-Catalyzed Direct Trifluoro- and Perfluoroalkylselenolations of Boronic Acids with a Shelf-Stable Family of Reagents.  [5]
Synthetic Approaches to Trifluoromethylselenolated Compounds. [6]
Trifluoromethylselenolation and Fluoroalkylselenolation of Alkenes by Electrophilic Addition. [7]
References:
[1] E.Magnier, C.Wakselman, Collect. Czech. Chem. Commun., 2002, 67, pp 1262-1266.
[2] Q.Glenadel, E. Ismalaj, T. Billard, J. Org. Chem., 2016, 81(18), pp 8268-8275.
[3] Q.Glenadel, E. Ismalaj, T. Billard, Eur. J. Org. Chem., 2017, 2017(3), pp 530-533.
[4] C.Ghiazza, T. Billard, A.Tlili, Chem. Eur. J., 2017, 23(42), pp 10013-10016.
[5] Q.Glenadel,C.Ghiazza, A.Tlili, T.Billard, Adv. Synth. Catal., 2017, 359(19), pp 3414-3420.
[6] A.Tlili, E.Ismalai, Q.Glenadel, C. Ghiazza,T.Billard, Chem. Eur. J., 2017.
[7] C.Ghiazza, Q. Glenadel, A.Tlili, Eur. J. Org. Chem., 2017, 26, pp 3812-3814.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
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