Tetramethylammonium trifluoromethylselenate((Me4N)SeCF3) is a one-pot procedure,beach-stable,operationally simple and highly selective nucleophilic reagent for trifluoromethylselenolated compounds. It can used as a direct trifluoromethylselenolation source to react at room temperature with various substrates, such as (hetero)aromatic amines,terminal alkynes,aryl bronic acids drivatives,(hetero)aryl halides, and α-diazo esters, etc..
Stable trifluoromethylselenates(0), [A]SeCF3—synthesis, characterizations and properties. 
Copper catalyzed oxidative coupling reactions for trifluoromethylselenolations – synthesis of R-SeCF3 compounds using air stable tetramethylammonium trifluoromethylselenate. 
Sandmeyer-Type Trifluoromethylthiolation and Trifluoromethylselenolation of (Hetero)Aromatic Amines Catalyzed by Copper. 
Trifluoromethylthiolation and Trifluoromethylselenolation of α-Diazo Esters Catalyzed by Copper. 
Expeditious trifluoromethylthiolation and trifluoromethylselenolation of alkynyl(phenyl)iodoniums by [XCF3]− (X = S, Se) anions.
Nickel-Catalyzed Trifluoromethylselenolation of Aryl Halides Using the Readily Available [Me4N][SeCF3] Salt. 
Divergent Reactivity of a Dinuclear (NHC)Nickel(I) Catalyst versus Nickel(0) Enables Chemoselective Trifluoromethylselenolation. 
Copper-catalyzed synthesis of 2,2-difluoro-1,3-benzoxathioles(selenoles) and their insecticidal activities: the selenium effect. 
Catalyst- and Additive-Free Trifluoromethylselenolation with [Me4N][SeCF3]. 
 W.Tyrra, et al, J. F. Chem., 2003, 123(2), pp 183-187.