Benzyl trifluoromethyl selenide

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
(Trifluoromethylseleno)methylbenzene
Trifluoromethylselenolating Reagents
KUMI3F51
186047-38-1
 
11368425
7804580
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Melting Point
Packaging
Storage
Benzyl trifluoromethyl selenide
C8H7F3Se
239.10
≥98.0%(HPLC)
Colorless to Light yellow Solid

5g,10g,50g,100g and 500g
Store at 2-8ºC temperature
Benzyl trifluoromethyl selenide is an electrophilic trifluoromethylselenolating reagent,which can introduce the SeCF3 moiety into a large variety of nucleophilies in a one-pot,two-step procedure. It is also used as a practical precursor for preparation of trifluoromethaneselenyl chloride in a mild condition.
A mild and practical preparation of trifluoromethaneselenenyl chloride. [1]
Benzyltrifluoromethyl (or Fluoroalkyl) Selenide: Reagent for Electrophilic Trifluoromethyl (or Fluoroalkyl) Selenolation. [2]
Electrophilic Trifluoromethyl- and Fluoroalkylselenolation of Organometallic Reagents. [3]
Trifluoromethyl- and Fluoroalkylselenolations of Alkynyl Copper(I) Compounds. [4]
Copper-Catalyzed Direct Trifluoro- and Perfluoroalkylselenolations of Boronic Acids with a Shelf-Stable Family of Reagents.  [5]
Synthetic Approaches to Trifluoromethylselenolated Compounds. [6]
Trifluoromethylselenolation and Fluoroalkylselenolation of Alkenes by Electrophilic Addition. [7]
References:
[1] E.Magnier, C.Wakselman, Collect. Czech. Chem. Commun., 2002, 67, pp 1262-1266.
[2] Q.Glenadel, E. Ismalaj, T. Billard, J. Org. Chem., 2016, 81(18), pp 8268-8275.
[3] Q.Glenadel, E. Ismalaj, T. Billard, Eur. J. Org. Chem., 2017, 2017(3), pp 530-533.
[4] C.Ghiazza, T. Billard, A.Tlili, Chem. Eur. J., 2017, 23(42), pp 10013-10016.
[5] Q.Glenadel,C.Ghiazza, A.Tlili, T.Billard, Adv. Synth. Catal., 2017, 359(19), pp 3414-3420.
[6] A.Tlili, E.Ismalai, Q.Glenadel, C. Ghiazza,T.Billard, Chem. Eur. J., 2017.
[7] C.Ghiazza, Q. Glenadel, A.Tlili, Eur. J. Org. Chem., 2017, 26, pp 3812-3814.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
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