Silver(I) Trifluoromethanethiolate

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
Trifluoromethanethiol Silver(I) Salt,Silver trifluoromethylsulfide
Trifluoromethythiolating Reagents
KUMI3F04
811-68-7
MFCD25563234
15972162
4151922
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay(Analysis Method)
Appearance
Melting Point
Packaging
Storage
Silver(I) Trifluoromethanethiolate
CAgF3S
208.93
≥95.0%(T)
Colorless to Grey Solid

5g,10g,50g,100g and 500g
Store at room temperature
Silver(I) Trifluoromethanethiolate is a trifluoromethylthiolating reagent usable for Direct Dehydroxytrifluoromethylthiolation of Alcohols.
Preparation of Trifluoromethyl Aryl Sulfides Using Silver(I)Trifluoromethanethiolate and an Inorganic Iodide.[1]
Pd-Catalyzed Synthesis of Ar-SCF3 Compounds under Mild Conditions.[2]
Silver-Mediated Radical Aryltrifluoromethylthiolation of Activated Alkenes. [3]
Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide.[4]
References:
[1] D.J.Adams,J.H.Clark,J.Org.Chem.,2000,65(5),pp 1456-1460.
[2] G.Teverovskiy,D.S.Surry,S.L.Buchwald,Angew. Chem.Int.Ed.,2011,50(32) pp 7312-7314.
[3] F.Yin,X.-S. Wang,Org. Lett.,2014,16(4),pp 1128-1131.
[4] J.-B.Liu,X.-H.Xu,Z.-H.Chen,F.-L.Qing,Angew. Chem. Int. Ed.,2015,54(3),pp 897-900.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Warning
H302+H312,H315,H319
P280,P305+P351+P338
2843.29.0100
NONH for all modes of transport

1. Product Specification
2. Safety Data Sheet
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