Benzoyl(phenyliodonio)(trifluoromethanesulfonyl)methanide

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem SID
Reaxys RN
Shibata Reagent II
Trifluoromethylthiolating Reagents
KUMI3F28
1443036-49-4
 
253660511
23755623
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay(Analysis Method)
Appearance
Melting Point
Packaging
Storage
Benzoyl(phenyliodonio)(trifluoromethanesulfonyl)methanide
C15H10F3IO3S
454.20
≥98.0%(HPLC)
Slight pale yellow to White Solid
102-104°C
1g,5g,10g and 50g
Store at room temperature
Shibata Reagent II is a novel Electrophilic-Type Trifluoromethylthiolating Reagent.
Trifluoromethanesulfonyl hypervalent iodonium ylide for copper-catalyzed trifluoromethylthiolation of enamines, indoles, and β-keto esters.[1]
Copper-Catalyzed Regioselective Trifluoromethylthiolation of Pyrroles by Trifluoromethanesulfonyl Hypervalent Iodonium Ylide.[2]
Trifluoromethylthiolation of allylsilanes and silyl enol ethers with trifluoromethanesulfonyl hypervalent iodonium ylide under copper catalysis.[3]
Reactions of allyl alcohols and boronic acids with trifluoromethanesulfonyl hypervalent iodonium ylide under copper-catalysis.[4]
References:
[1] Y.-D.Yang, A.Azuma, E.Tokunaga, M.Yamasaki ,M.Shiro, N.Shibata, J.Am.Chem.Soc., 2013, 135(24), pp 8782-8785.
[2] Z.-Y.Huang, Y.-D.Yang, E.Tokunage, N.Shibata, Org. Lett., 2015, 17 (5), pp 1094–1097.
[3] S.Arimori, M.Takada, N.Shibata, Org. Lett., 2015, 17 (5), pp 1063-1065.
[4] S.Arimori, M.Takada, N.Shibata, Dalton Trans., 2015, 44(45), pp 19456-19459.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Danger
H314
P260,P264,P280,P305+P351+P338+P310
2931.90.9050
UN 1759 8 PG II

1. Product Specification
2. Safety Data Sheet
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