[(2,2′-bipyridine)Cu(SCF3)]

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem SID
Reaxys RN
(bpy)Cu(trifluoromethylthio),(bpy)CuSCF3
Trifluoromethylthiolating Reagents,Trifluoromethylating Reagents
KUMI3F21
1413732-47-4
 

23254427
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Melting Point
Packaging
Storage
[(2,2′-bipyridine)Cu(SCF3)]
C11H8CuF3N2S
320.80
≥97.0%
Red Solid

1g,5g,10g and 50g
Store at room temperature
(bpy)CuSCF3 is an air-stable copper reagent for nucleophilic trifluoromethylthiolation of aryl halides and ketones.
An Air-Stable Copper Reagent for Nucleophilic Trifluoromethylthiolation of Aryl Halides.[1]
Room temperature nucleophilic trifluoromethylthiolation of benzyl bromides with (bpy)Cu(SCF3).[2]
An Improved Protocol for the Synthesis of α-Trifluoromethylthio-Substituted Ketones by Copper-Mediated Trifluoromethylthiolation of α-Bromo Ketones. [3]
Copper-Mediated Trifluoromethylthiolation of Heteroaryl Bromides.[4]
Development of Multigram Scale Synthesis of Trifluoromethylthiolating Reagent: (bpy)CuSCF3. [5]
References:
[1] Weng Z. et al, Angew.Chem. Int.Ed.2013,vol. 52. # 5 p.1548-1552.
[2] Kong D. et al, Tetrahedron, 2013,vol.69, # 30 p. 6046 - 6050.
[3] Huang Y. et al,Euro. J. of Org. Chem., 2014, vol. 2014, # 33 p.7324 - 7328.
[4] Zhang M. et al, Adv. Syn. and Cata., 2016,vol. 358, # 3 p. 386 - 394.
[5] Zhang Y. et al, Org. Proc. R&D, 2016, vol. 20,  # 4 p. 799 - 802.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Warning
H302+H312,H315,H319
P280,P305+P351+P338

NONH for all modes of transport

1. Product Specification
2. Safety Data Sheet
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