Trifluoromethyl arylsulfonate (TFMS) is a class of novel trifluoromethoxylating reagents,used as a new trifluoromethoxylation reagent for an asymmetric silver-catalysed intermolecular bromotrifluoromethoxylation of alkenes. Compared to other trifluoromethoxylating reagents, TFMS is easily prepared and thermally stable with good reactivity. In addition, this reaction is operationally simple, scalable and proceeds under mild reaction conditions.
Asymmetric silver-catalysed intermolecular bromotrifluoromethoxylation of alkenes with a new trifluoromethoxylation reagent.
 S. Guo, F. Cong, R.Guo, L. Wang, P. Tang, Nat. Chem., 2017, 9, PP 546-551.
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