Trifluoromethyl 2,4,6-triisopropylbenzenesulfonate

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
Benzenesulfonic acid,2,4,6-tris(1-methylethyl)-,trifluoromethyl ester
O-Trifluoromethylating Reagents,Trifluoromethoxylating reagents
KUMI3F31
2074633-37-5
 
123131865

image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Boiling Point
Packaging
Storage
Trifluoromethyl 2,4,6-triisopropylbenzenesulfonate
C16H23F3O3S
352.41
≥97.0%(GC)
Liquid
336.5±42.0°C
5ml,10ml,50ml,100ml and 500ml 
Store at room temperature
Trifluoromethyl arylsulfonate (TFMS) is a class of novel trifluoromethoxylating reagents,used as a new trifluoromethoxylation reagent for an asymmetric silver-catalysed intermolecular bromotrifluoromethoxylation of alkenes. Compared to other trifluoromethoxylating reagents, TFMS is easily prepared and thermally stable with good reactivity. In addition, this reaction is operationally simple, scalable and proceeds under mild reaction conditions.
Asymmetric silver-catalysed intermolecular bromotrifluoromethoxylation of alkenes with a new trifluoromethoxylation reagent.[1]
Reference:
[1] S. Guo, F. Cong, R.Guo, L. Wang, P. Tang, Nat. Chem., 2017, 9, PP 546-551.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
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