N-(benzenesulfonyl)-N-[(trifluoromethyl)sulfanyl]benzenesulfonamideis a new, shelf-stable,broadly applicable electrophilic trifluoromethylthiolating reagent typically reacting with a wide range of electron-rich arenes and activated heteroarenes under mild conditions. It is also used for the preparation of other SCF3-containing compounds, such as trifluoromethylthiolated styrenes, oxo-trifluoromethylthio and amino-trifluoromethylthio difunctionalized compounds, etc..
N-Trifluoromethylthio-dibenzenesulfonimide: A Shelf-Stable, Broadly Applicable Electrophilic Trifluoromethylthiolating Reagent. 
Enantioselective Trifluoromethylthiolating Lactonization Catalyzed by an Indane-Based Chiral Sulfide. 
Trifluoromethylthiolation-Based Bifunctionalization of Diazocarbonyl Compounds by Rhodium Catalysis. 
Preparation of Electrophilic Trifluromethylthio Reagents from Nucleophilic Tetramethylammonium Trifluoromethylthiolate. 
Chiral Selenide-Catalyzed Enantioselective Allylic Reaction and Intermolecular Difunctionalization of Alkenes: Efficient Construction of C-SCF3 Stereogenic Molecules. 
Diastereoselective Electrophilic Trifluoromethylthiolation of Chiral Oxazolidinones: Access to Enantiopure α-SCF3 Alcohols. 
 P.Zhang, et al, J. Org. Chem., 2016, 81(17), pp 7486-7509.