N-(benzenesulfonyl)-N-[(trifluoromethyl)sulfanyl]benzenesulfonamide 

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
Bis(phenylsulfonyl)(trifluoromethylthio)amine
Trifluoromethylthiolating Reagents
KUMI3F205
1902154-93-1

132546519
1868911
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Boiling Point
Packaging
Storage
N-(benzenesulfonyl)-N-[(trifluoromethyl)sulfanyl]benzenesulfonamide
C13H10F3NO4S3
397.40
≥98%
Colorless to Pale yellow Liquid
>380°C
5g,10g,25g,50g,100g and 500g
Store at room temperature
N-(benzenesulfonyl)-N-[(trifluoromethyl)sulfanyl]benzenesulfonamide is a new, shelf-stable,broadly applicable electrophilic trifluoromethylthiolating reagent typically reacting with a wide range of electron-rich arenes and activated heteroarenes under mild conditions. It is also used for the preparation of other SCF3-containing compounds, such as trifluoromethylthiolated styrenes, oxo-trifluoromethylthio and amino-trifluoromethylthio difunctionalized compounds, etc..
N-Trifluoromethylthio-dibenzenesulfonimide: A Shelf-Stable, Broadly Applicable Electrophilic Trifluoromethylthiolating Reagent. [1]
Enantioselective Trifluoromethylthiolating Lactonization Catalyzed by an Indane-Based Chiral Sulfide. [2]
Trifluoromethylthiolation-Based Bifunctionalization of Diazocarbonyl Compounds by Rhodium Catalysis. [3]
Preparation of Electrophilic Trifluromethylthio Reagents from Nucleophilic Tetramethylammonium Trifluoromethylthiolate. [4]
Chiral Selenide-Catalyzed Enantioselective Allylic Reaction and Intermolecular Difunctionalization of Alkenes: Efficient Construction of C-SCF3 Stereogenic Molecules. [5]
Diastereoselective Electrophilic Trifluoromethylthiolation of Chiral Oxazolidinones: Access to Enantiopure α-SCF3 Alcohols. [6]
References:
[1] P.Zhang, et al, J. Org. Chem., 2016, 81(17), pp 7486-7509.
[2] X.Liu, et al, Angew. Chem. Int. Ed., 2016, 55(19), pp 5846-5850.
[3] M.Lubcke, et al, Org. Lett., 2017, 19(17), pp 4548-4551.
[4] S.Kovacs, et al, Adv. Synth. Catal., 2017, 359(2), pp 250-254.
[5] X.Liu, et al, J. Am. Chem. Soc., 2018, 140(14), pp 4782-4786.
[6] H.Chachignon, et al, Adv. Synth. Catal., 2018, 360(5), pp 965-971.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Not classified as a hazardous substance or mixture


29359090990
NONH for all modes of transport

1. Product Specification
2. Safety Data Sheet
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