1,​1,​1-​Trifluoro-​1-​methyl-​1-​phenylethyl ester methanesulfenic acid 

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
2-(Trifluoromethylsulfanyloxy)propan-2-ylbenzene
Trifluoromethylthiolating Reagents
KUMI3F207
1640084-14-5

121540554
27362383
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Boiling Point
Packaging
Storage
1,​1,​1-​Trifluoro-​1-​methyl-​1-​phenylethyl ester methanesulfenic acid
C10H11F3OS
236.25
≥98%
Colorless to Pale yellow Liquid
190°C
5g,10g,25g,50g,100g and 500g
Store at room temperature
1,​1,​1-​Trifluoro-​1-​methyl-​1-​phenylethyl ester methanesulfenic acid is a useful electrophilic trifluoromethythiolating reagent in tolerance with various functional groups for the synthesis of the trifluoromethylthiolated compounds of interest.
Copper-catalyzed trifluoromethylthiolation of primary and secondary alkylboronic acids. [1]
N-trifluoromethylthiosaccharin: An easily accessible, shelf-stable, broadly applicable trifluoromethylthiolating reagent. [2]
Trifluoromethyl sulfoxides from allylic alcohols and electrophilic SCF3 Donor by [2,3]-sigmatropic rearrangement. [3]
Iron-mediated Markovnikov-selective hydro-trifluoromethylthiolation of unactivated alkenes. [4]
Visible Light-Promoted Decarboxylative Di- A nd Trifluoromethylthiolation of Alkyl Carboxylic Acids. [5]
A General Strategy for Aliphatic C-H Functionalization Enabled by Organic Photoredox Catalysis. [6]
References:
[1] X.Shao, et al, Org. Lett., 2014, 16(18), pp 4738-4741.
[2] C.Xu, et al, Angew. Chem. Int. Ed., 2014, 53(35), pp 9316-9320.
[3] M.Maeno, et al, Org. Lett., 2015, 17(8), pp 1990-1993.
[4] T.Yang, et al, Chem. Commun., 2015, 51(25), pp 5479-5481.
[5] L.Candish, et al, Chem. Eur. J., 2016, 22(14), pp 4753-4756.
[6] K.A.Margrey, et al, J. Am. Chem. Soc., 2018, 140(12), pp 4213-4217.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Danger
H228,H315,H319,H335
P210,P261,P305+P351+P338

UN 1325 4.1/PG III

1. Product Specification
2. Safety Data Sheet
Please inquire for pricing and availability of this product by writing email to sales@kumidas.com.