Trifluoromethyl trifluoromethanesulfonate

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
Trifluoromethyl triflate, Trifluoromethanesulfonic acid trifluoromethyl ester
Trifluoromethoxylating Reagents
KUMI6F14
3582-05-6
MFCD04973017
337239
1873886
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Boiling Point
Packaging
Storage
Trifluoromethyl trifluoromethanesulfonate
C2F6O3S
218.08
≥98%(GC)
Colorless to Light-yellow Liquid (Liquified gas)
19-21°C
5g,10g,25g,50g,100g,250g,500g and 1kg
Store 2-8°C
Trifluoromethyl trifluoromethanesulfonate(TFMT) is a useful trifluoromethoxylating reagent as an in situ generator of the trifluoromethoxide anion.
Versatile application of trifluoromethyl triflate. [1]
Silver-mediated direct trifluoromethoxylation of α-diazo esters via the OCF3 anion. [2]
New Reagents for Asymmetric Trifluoromethoxylation. [3]
Theoretical and experimental study of a new thiosulfonate derivative: Methyl trifluoromethanethiosulfonate, CF3SO2SCH3. Conformational transferability in CX3SO2S-R compounds. [4]
References:
[1] A.A.Kolomeitsev, et al, Tetrahedron Lett., 2008, 49(3), pp 449-454.
[2] G.F.Zha, et al, Chem. Commun., 2016, 52(47), pp 7458 - 7461.
[3] F.Toulgoat, et al, Chem., 2017, 2(5), pp 327-329.
[4] J.E.Galvan, et al, Inorg. Chim. Acta, 2017, 455, pp 254-261.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Danger
H302+H312,H314,H331,H335
P260,P264,P280,P303+P361+P353
29051900
UN3265 8/PG III

1. Product Specification
2. Safety Data Sheet
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