Trifluoromethyl arylsulfonate (TFMS) is a class of novel trifluoromethoxylating reagents, used as new and efficient precursors for an asymmetric silver-catalysed intermolecular bromotrifluoromethoxylation of alkenes. Compared to other trifluoromethoxylating reagents, TFMS is easily prepared and thermally stable with good reactivity. In addition, this reaction is operationally simple, scalable and proceeds under mild reaction conditions.
Palladium-catalyzed amination of aryl bromides and aryl triflates using diphosphane ligands: A kinetic study. 
Acid-mediated formation of trifluoromethyl sulfonates from sulfonic acids and a hypervalent iodine trifluoromethylating agent.
Asymmetric silver-catalysed intermolecular bromotrifluoromethoxylation of alkenes with a new trifluoromethoxylation reagent.