2,2,2-Trifluoroethyl trifluoromethanesulfonate (also named as Trifluoromethanesulfonic acid 2,2,2-trifluoroethyl ester, Trifluoroethanol triflate) is a powerful trifluoroethylating agent typically used for synthesis of fluorinated amino acids. It is also used as a reagent in thenantioselective preparation of cyclic N-aryl hydroxamic acids via phase-transfer catalyzed alkylation of nitrobenzyl bromides to give nirophenylalanines.
A facile synthesis of 1-H-2,2-difluorovinylphosphorus compounds from 2,2,2-trifluoroethyl trifluoromethanesulfonate and substitutions of their vinylic fluorines. 
A general strategy for the synthesis of cyclic N-aryl hydroxamic acids via partial nitro group reduction. 
 J.Ichikawa, et al, J. F. Chem., 1999, 97(1-2), pp 109-114.
 L.A.McAllister, et al, J. Org. Chem., 2011, 76(9), pp 3484-3497.
UN 3265 8/PG II
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