≥98.0% (Indirect iodimetry, Active Fluorine Content ≥5.25%)
White to Off-white Powder
5g,10g,20g,50g,100g,250g,500g,1kg,5kg and 25kg
Store at room temperature
N-Chloromethyl-N′-fluorotriethylenediammonium bis(tetrafluoroborate) (also named as SelectFluor, F-TEDA-BF4) is a safe, nontoxic and easy to handle electrophilic N-F type fluorinating reagent, typically used for greener fluorination of acetoacetamides in PEG-400. This reagent rapidly fluorinates a wide range of organic molecules under mild conditions with high efficiency and selectivity.
Regioselective Fluorohydroxylation Reaction of Arylallenes.
Regiospecific fluorination of functionalized phenols.
Catalyst-free and highly selective electrophic mono-fluorination of acetoacetamides in PEG-400.
Metal-Free Fluorination of C(sp3)-H Bonds using a Catalytic N-Oxyl Radical.
Solvent‐Free Fluorination of Electron‐Rich Aromatic Compounds with F‐TEDA‐BF4: Toward “Dry” Processes.
Fluorination‐Oxidation of 2‐Hydroxymethylindole Using Selectfluor.
 C.Zhou, et al ,Org. Lett. 2008, 10(4), pp 581-583.
 T.Furuya, et al, J. Am. Chem. Soc., 2009, 13(5), pp 1662-1663.
 G.Zhang, et al, Green Chem., 2012, 4(14), pp 1159-1162.
 Y.Amaoka, et al, M. Inoue, Org. Lett., 2013, 15(9), pp 2160-2163.
 P.A.Zaikin, et al, Eur. J. Org. Chem., 2017, 17, pp 2469-2474.